Class 12 · Notes

Semiconductor Electronics— Notes, Formulas & Revision

Complete revision notes and formulas for Semiconductor Electronics (Class 12). Curated for JEE, NEET, AP Physics, SAT, and CUET. Tap any topic to open the live simulation and full PYQ set.

Energy Band Diagram

Valence and conduction bands split by E_g — tune T to see thermal excitation follow exp(−E_g/2kT).

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In a solid, atomic energy levels broaden into BANDS due to overlap of electron wavefunctions.

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Valence band: highest filled (or partially filled) band at T = 0. Conduction band: next higher (mostly empty).

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Energy gap E_g = bottom of conduction band − top of valence band.

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Conductors: bands overlap or valence band partially filled ⇒ free electrons readily move. Eg ≈ 0.

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Insulators: large gap (E_g > ~3 eV). Few electrons can be thermally excited to the CB.

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Semiconductors: small gap (E_g ~ 0.5-2 eV). Some thermal excitation at room temperature.

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Conduction in semiconductors involves BOTH electrons in CB and HOLES (missing electrons in VB) — holes act like positive charge carriers.

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Doping creates extra states INSIDE the gap close to CB (donor → n-type) or VB (acceptor → p-type), dramatically changing conductivity.

Carrier density (intrinsic)

Strongly temperature-dependent — small E_g ⇒ more carriers.

Conductivity

n = electron density, p = hole density, μ = mobility.

Band gaps (room T)

Determines wavelength of LED light (E_g = hc/λ).

BAND structure is the language of semiconductor physics. Memorise: conductor (overlap), semiconductor (small gap), insulator (big gap).

Carrier density in intrinsic Si at room T: n_i ≈ 10¹⁶/m³ — extremely small compared to metals (~10²⁸).

Increasing T excites more carriers into CB ⇒ conductivity INCREASES (opposite of metals).

Doping with one part per million can change resistivity by 6+ orders of magnitude — that's why semiconductor industry exists.

Direct vs indirect bandgap: direct (GaAs) ⇒ efficient light emission/absorption. Indirect (Si) ⇒ inefficient ⇒ Si LEDs are uncommon.

Fermi level: at the middle of E_g for intrinsic semiconductors; shifts toward CB for n-type, toward VB for p-type.

Conductor vs Insulator vs Semiconductor

Three-panel side-by-side band comparison with resistivity labels.

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CLASSIFICATION of solids by electrical conductivity / band structure:

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Conductors (metals): partially filled or overlapping bands; resistivity ~10⁻⁸ Ω·m; conductivity DECREASES with temperature.

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Insulators: large bandgap (E_g > 3 eV); resistivity 10⁸-10¹⁶ Ω·m; essentially no free carriers at room temperature.

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Semiconductors: small bandgap (0.5-2 eV); resistivity 10⁻⁴-10⁴ Ω·m; conductivity INCREASES with temperature.

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Conductivity range spans ~24 orders of magnitude across these classes — most extreme variation in all of solid-state physics.

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Doping makes semiconductors functionally indispensable — controllable conductivity by orders of magnitude.

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Examples: Cu, Ag, Au (conductors); diamond, rubber, glass (insulators); Si, Ge, GaAs (semiconductors).

Resistivity ranges (rough)

Reference values at room temperature.

Temperature dependence

Opposite behaviour: metals heat up = harder; semiconductors heat up = easier.

Conductivity differs by 20+ orders of magnitude across classes — the most extreme range in physics.

Metals: resistance rises with T (phonon scattering). Semiconductors: resistance FALLS with T (more carriers).

Carbon: graphite is a (semi-)metal; diamond is an insulator. Same element, very different bandgaps.

Doping a semiconductor moves it dramatically toward metallic conductivity without changing it crystalographically.

Superconductors: zero resistance below T_c. Distinct from metals — not just better conductors.

Plastic / amorphous semiconductors are now used in flexible electronics, OLEDs, etc.

Intrinsic Semiconductor

Pure Si lattice — thermal breaking of covalent bonds creates e⁻/hole pairs (n=p=n_i).

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An INTRINSIC semiconductor is pure — no dopants. Examples: ultra-pure Si and Ge.

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At T = 0 K: VB fully filled, CB empty ⇒ behaves as insulator.

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At room T: a few electrons thermally excited to CB, leaving an equal number of HOLES in VB ⇒ n = p = n_i.

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Carrier density depends exponentially on temperature: n_i ∝ T^(3/2) · exp(−E_g/2k_BT).

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For intrinsic Si at 300 K: n_i ≈ 1.5 × 10¹⁰/cm³. For Ge: ~2.4 × 10¹³/cm³.

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Holes drift in the OPPOSITE direction to electrons in an applied field ⇒ both contribute to current in the SAME direction.

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Intrinsic conductivity at room T is too small for practical devices ⇒ doping is essential.

Carrier density

Strongly T-dependent.

Mass-action law

Valid in any semiconductor at equilibrium (also for doped).

Intrinsic conductivity

Both electrons and holes contribute.

n_i values (room T)

Reference numbers.

n = p in intrinsic semiconductors — equal numbers of electrons and holes.

Conductivity is highly sensitive to temperature — intrinsic Si conductivity doubles roughly every 10°C.

Holes are NOT real particles — they are vacancies in the VB that behave as effective + charges.

Electron and hole mobilities differ: μ_e > μ_h typically (~1350 vs 480 cm²/V·s in Si).

Practical use of intrinsic semiconductors: thermistors (R drops fast with T), photoresistors (light creates carriers).

Doping increases conductivity ENORMOUSLY at the cost of breaking n = p.

Extrinsic (n-type & p-type)

Doping with pentavalent P (extra e⁻) or trivalent B (extra hole) — toggle type live.

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Extrinsic semiconductor = intrinsic + dopants. Two types:

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n-type: doped with Group V element (P, As, Sb) — has one EXTRA valence electron ⇒ donates to CB.

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Donor level is just below CB. Even at low T, donors ionise easily ⇒ many free electrons.

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p-type: doped with Group III (B, Ga, Al) — has one FEWER valence electron ⇒ creates HOLES in VB.

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Acceptor level is just above VB. Electrons easily jump from VB to acceptor ⇒ many free holes.

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Majority carriers: n-type → electrons; p-type → holes. Minority carriers are the opposite.

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Mass-action law: n·p = n_i² always holds. In doped: one carrier is much larger than n_i, the other much smaller.

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Doping concentrations are tiny (1 part per million or less) but change conductivity by ~10⁶ ×.

n-type (heavy doping)

N_D = donor concentration. Holes become minority.

p-type (heavy doping)

N_A = acceptor concentration. Electrons become minority.

Conductivity

Dominated by majority carriers.

Mass-action law

Universal — even when n and p are very different.

Doping is the basis of all semiconductor devices — diodes, transistors, ICs.

Even 1 dopant per 10⁹ host atoms changes conductivity enormously.

n-type and p-type are both ELECTRICALLY NEUTRAL — the donor ion (+) balances the donated electron (−), and similarly for acceptors.

Doping levels typically 10¹⁵-10²⁰/cm³ — far below 10²² atoms/cm³ of the host.

At low T, dopant ionisation is partial (carrier freeze-out); at high T, n_i becomes comparable to N_D/N_A and intrinsic behaviour dominates.

Useful range of T for doped Si: ~150 K to ~450 K — beyond which intrinsic or freeze-out behaviour kicks in.

PN Junction

Depletion region, built-in V_bi = 0.7 V — apply forward/reverse bias and see width change.

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A p-n junction is formed by joining p-type and n-type semiconductors (in a single crystal, not metal contact).

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Diffusion: electrons from n-side diffuse to p-side; holes from p-side diffuse to n-side. Diffusion currents flow.

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Diffusion leaves IONISED dopants behind — a DEPLETION region (charge-depleted of mobile carriers) forms at the junction.

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The ionised donors (positive) and acceptors (negative) create a built-in electric field that OPPOSES further diffusion ⇒ equilibrium.

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Built-in potential V₀ (~0.6-0.7 V for Si, ~0.3 V for Ge) is the equilibrium contact potential.

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Forward bias (p connected to +): reduces V₀ and depletion width ⇒ large current flows.

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Reverse bias (p connected to −): increases V₀ and depletion width ⇒ tiny saturation current.

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This asymmetry makes the p-n junction a DIODE — passes current one way, blocks the other.

Built-in potential

Depends on doping levels and intrinsic concentration.

Depletion width

Wider for lower doping; shrinks with forward bias.

Diode equation (Shockley)

Forward bias: I grows exponentially. Reverse: I ≈ −I₀ (saturation).

The depletion region is essentially insulating — only ionised dopants, no mobile carriers.

Built-in V₀ does NOT appear at the external terminals — internal to the crystal.

Forward bias: current rises steeply once V > V_th ≈ 0.7 V (Si).

Reverse bias: I ≈ −I₀ (~nA to μA); independent of |V| until breakdown.

Reverse breakdown: large V_R causes avalanche or Zener breakdown ⇒ large I; used in voltage regulators (Zener diodes).

p-n junctions are the foundation of ALL semiconductor devices: diodes, BJTs, LEDs, solar cells, photodiodes.

Diode I-V Characteristics

Shockley: I = I_s(exp(V/V_T)−1) — knee at ~0.7 V Si; tiny reverse current.

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A p-n junction diode has an asymmetric I-V curve: ALMOST NO current in reverse, EXPONENTIAL current in forward.

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Forward characteristic: current is negligible until V ≈ V_threshold (knee voltage, ~0.7 V Si, ~0.3 V Ge), then rises steeply.

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Reverse characteristic: tiny saturation current I₀ (nA-μA) until BREAKDOWN voltage, where current suddenly grows.

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Static resistance R = V/I (depends on operating point). Dynamic (small-signal) resistance r_d = dV/dI = k_BT/(eI) at room temperature.

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Ideal diode: zero forward resistance, infinite reverse resistance — used in idealized circuit analysis.

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Real diode has a 'knee' due to V_threshold and finite forward slope (a few Ω).

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Breakdown mechanisms: Zener (tunnelling, low V_BR, < 5V) and avalanche (impact ionisation, high V_BR).

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Special diodes: LED (light emission), photodiode (photocurrent), Zener (voltage reference), Schottky (low V_F), tunnel diode.

Shockley diode equation

Exponential growth in forward; saturation in reverse.

Threshold (knee) voltage

Below threshold, current is negligible.

Static resistance

Falls with V in forward bias (non-Ohmic).

Dynamic resistance

Useful for small-signal analysis. At I = 1 mA, r_d = 26 Ω.

Diode is NON-LINEAR — Ohm's law does not apply.

V_threshold ~ 0.7 V for Si is rounded. Real-world diodes show forward conduction from ~0.5 V.

Reverse current is mostly thermally generated minority carriers — strongly T-dependent.

Dynamic resistance r_d falls with current — at high I, very low resistance.

Schottky diodes (metal-semiconductor) have V_F ~ 0.2 V and very fast switching — used in switching power supplies.

Reverse breakdown is NOT necessarily damaging if current is limited externally; Zener diodes exploit it.

Half-Wave Rectifier

Single diode — V_out = max(0, V_in − 0.7) with live oscilloscope trace.

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Half-wave rectifier: a single diode in series with a load lets only one HALF of the AC cycle pass.

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During the positive half of input AC: diode forward-biased, current flows.

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During the negative half: diode reverse-biased, blocks current (output = 0).

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Output is a series of positive pulses, not smooth DC.

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Average (DC) output voltage: V_dc = V_m/π ≈ 0.318 V_m, where V_m is the input peak.

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RMS output: V_rms = V_m/2 (over the full cycle).

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Ripple factor (RMS of AC component / DC) for half-wave: ~1.21 — very poor; needs heavy filtering.

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PIV (Peak Inverse Voltage) the diode must withstand: V_m.

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Efficiency: ~40.6% — poor. Half-wave is used only when simplicity matters and load draws little current.

DC output (no filter)

Time-average of V_m·sin(ωt) over a full cycle, accepting only positive half.

RMS output (no filter)

Half of the full-cycle RMS.

Ripple factor

Ratio of AC ripple to DC component.

Efficiency

Theoretical max for ideal half-wave with resistive load.

PIV

Maximum reverse voltage across the diode.

Half-wave is the simplest rectifier — but inefficient. Used for AC-DC adapters drawing < 100 mA.

Output frequency = input frequency (50 Hz from 50 Hz mains).

Filter capacitor smooths the pulses but ripple remains worse than for full-wave.

Half-wave wastes the negative half of the cycle — only one pulse per period, vs two for full-wave.

Common pitfall: confusing V_dc (average) with V_rms — they are different things, both important.

Real diode drops ~0.7 V — so for low-voltage rectification, peak output is V_m − 0.7 V, not V_m.

Full-Wave Rectifier

Bridge of 4 diodes — V_out = |V_in| − 1.4 V with optional capacitor filter.

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A full-wave rectifier inverts the negative half of the AC cycle, producing pulses for BOTH halves.

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Two common topologies: (i) Centre-tapped transformer with 2 diodes; (ii) bridge rectifier with 4 diodes (no centre tap).

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Output frequency = 2× input frequency (100 Hz from 50 Hz mains).

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Average (DC) output: V_dc = 2V_m/π ≈ 0.637 V_m. DOUBLE that of half-wave.

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RMS: V_rms = V_m/√2.

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Ripple factor: γ ≈ 0.482 — much better than half-wave's 1.21.

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Efficiency: ~81.2% — twice half-wave.

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PIV: 2V_m for centre-tap; V_m for bridge. Bridge is preferred because diode rating is half — but uses 4 diodes.

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Combined with a filter capacitor and (optionally) a voltage regulator, you get a usable DC supply.

DC output

Average over both rectified halves.

RMS output

Same as RMS of original sine wave (entire cycle utilised).

Ripple factor

Much better than half-wave.

Efficiency

Maximum theoretical for ideal diodes, resistive load.

PIV

Bridge wins on diode stress.

Bridge rectifier is the standard topology in modern power supplies — needs no center tap.

Output ripple at 2f (100 Hz in India) is easier to filter than 50 Hz half-wave ripple.

Adding a smoothing capacitor: output approaches V_m with small ripple proportional to 1/(fRC).

For Indian mains, 220 V_rms ⇒ V_m = 311 V ⇒ V_dc(no filter) ≈ 198 V, V_dc(capacitor-filtered) ≈ 310 V.

Diode forward drop: ~0.7 V per diode in conduction. Bridge has 2 diodes in series each half-cycle ⇒ 1.4 V drop.

Switching power supplies use high-frequency rectification — much smaller filter components.

Transistor (NPN, CE)

I_C = β · I_B — tune V_BB through cutoff, active, and saturation regions.

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A bipolar junction transistor (BJT) is a 3-terminal device with two p-n junctions: NPN or PNP. Terminals: Emitter (E), Base (B), Collector (C).

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NPN transistor in 'active' mode: E-B junction forward-biased, C-B junction reverse-biased.

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Emitter (heavily doped) injects electrons into Base (lightly doped, thin); most diffuse across to the Collector (moderately doped).

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Small base current I_B controls large collector current I_C — transistor is a CURRENT AMPLIFIER.

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Current gain β (or h_FE) = I_C/I_B; typically 50-300. α = I_C/I_E ≈ 0.99.

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Three operating regions: (i) Cutoff (both junctions reverse, transistor OFF). (ii) Active (E-B forward, C-B reverse, amplifies). (iii) Saturation (both forward, transistor 'ON' as a switch).

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Three common configurations: (i) Common-Emitter — high current AND voltage gain; (ii) Common-Base — voltage gain only; (iii) Common-Collector (emitter follower) — current gain, unity voltage gain, high input impedance.

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Applications: amplifiers, switches, oscillators, logic gates. Modern MOSFETs (field-effect) dominate ICs.

Current relations

Linked via β = α/(1−α). For α = 0.99: β = 99.

α-β relation

Small change in α → large change in β.

Voltage gain (CE)

Where g_m = I_C/V_T = I_C/(26 mV); negative sign = phase inversion.

Input vs output (CE)

Typical Si BJT values when ON / saturated.

BJT current GAIN, voltage gain comes from passive loads.

Common-Emitter (CE) configuration is the most-used amplifier: high A_V, high A_I, but phase inverts.

Saturation: V_CE drops to ~0.2 V, transistor acts as closed switch. Used in digital logic.

Cutoff: I_C ≈ 0, transistor acts as open switch.

β varies widely across transistors of the same part number — design for β = β_min for reliability.

MOSFETs vs BJTs: MOSFETs are voltage-controlled, BJTs current-controlled. MOSFETs win in digital ICs; BJTs in analog low-noise.

Logic Gates

AND, OR, NOT, NAND, NOR, XOR — toggle A/B and watch output LED + truth table.

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Logic gates are circuits whose output depends on Boolean inputs (HIGH/1 or LOW/0). Building blocks of all digital systems.

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Basic gates: AND, OR, NOT. Universal gates: NAND, NOR (any logic can be built from either alone).

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Truth tables define each gate's behaviour. AND: output 1 only if all inputs 1. OR: output 1 if any input 1. NOT: inverts input.

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XOR (exclusive OR): output 1 when inputs differ. XNOR: complement of XOR.

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DeMorgan's laws: (A·B)' = A' + B' and (A+B)' = A'·B'. Lets you convert AND into OR (with inversions) and vice versa.

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CMOS technology builds all logic from complementary p-MOS and n-MOS pairs — very low static power consumption.

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Standard CMOS voltages: V_DD = 3.3 V or 5 V; logic 0 < ~0.8 V, logic 1 > ~2.0 V (TTL levels).

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Combinational logic: output depends only on current inputs (adders, multiplexers). Sequential logic: output also depends on past (flip-flops, registers, memory).

AND

1 only when both inputs are 1.

OR

1 when at least one input is 1.

NOT (inverter)

Output is the inverse of input.

NAND

Universal — any Boolean function can be built from NANDs.

NOR

Universal — any Boolean function can be built from NORs.

XOR

1 when exactly one input is 1.

TRUTH TABLE is the unambiguous definition of a gate. Memorise the basic four.

NAND and NOR are UNIVERSAL: any digital circuit can be built using only NANDs (or only NORs).

AND: output 0 unless all 1 — like a 'series of switches'. OR: output 1 unless all 0 — 'parallel'.

XOR is a sum mod 2 — used in binary adders, parity checks, encryption.

Sequential logic uses gates + feedback to STORE state — flip-flops are the basic memory cell.

Real gates have propagation delay (~ns), so 'instantaneous' transitions are an idealisation.

Zener Diode (Regulator)

Sharp reverse breakdown at V_z = 5.1 V — output clamps once V_in exceeds V_z.

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A Zener diode is a heavily-doped p-n junction designed to operate in REVERSE BREAKDOWN.

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Below breakdown: behaves like normal diode (low reverse current).

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At V = V_Z (Zener voltage): reverse current suddenly grows, but voltage stays nearly constant.

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This sharp clamp at V_Z is exploited for VOLTAGE REGULATION — line voltage or load may vary, output stays at V_Z.

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Breakdown mechanisms: Zener effect (tunnelling, V_Z < ~5 V, has negative T-coefficient) vs avalanche (impact ionisation, V_Z > ~5 V, positive T-coefficient). At ~5 V both contribute and T-coefficient is minimal — used in temperature-stable references.

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Always operate with a SERIES RESISTOR to limit current. Otherwise the diode burns out at breakdown.

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Used in: voltage regulators, surge protectors, waveform clippers, reference voltages.

Zener current (in breakdown)

R_S = series limiting resistor; I_load = load current drawn from V_Z.

Power dissipation

Must stay below diode's rated max.

Regulation condition

Ensures the Zener stays in breakdown for all load conditions.

Zener diode regulates voltage by 'wasting' the excess as heat — efficient at low loads, less so at high.

Choose V_Z slightly above target output, and size R_S so that Zener current never drops below the minimum required for regulation.

Power rating matters — a 0.5 W Zener at 12 V can carry only ~42 mA max.

For high-power regulation, use a Zener as the REFERENCE for a transistor pass element (linear regulator) or move to switching supply.

Avalanche-mode Zeners (V_Z > 6 V) have positive temperature coefficient — Zener-mode (< 5 V) have negative. ~5-6 V Zeners are temperature-stable.

TVS (transient voltage suppressor) diodes are heavy-duty Zeners used for surge protection.

LED Behavior

λ = 1240/E_g — 5 materials from GaAs (IR) to InGaN (violet) with photon emission.

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Light-Emitting Diode (LED) = a forward-biased p-n junction (made of a direct-bandgap semiconductor) that emits light when electrons recombine with holes in the depletion region.

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Emitted photon energy ≈ E_g of the semiconductor ⇒ λ = hc/E_g.

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Material chooses colour: GaAs (IR, λ ~ 870 nm), GaAsP (red), GaP (green), GaN/InGaN (blue-UV), GaN+phosphor (white).

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Direct-bandgap materials (GaAs, GaN) make efficient LEDs; indirect-bandgap (Si) emit very little light.

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Forward voltage V_F depends on colour: red ~1.8 V, green ~2.2 V, blue ~3.0 V, UV ~3.5+ V.

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LED current must be limited externally (resistor or constant-current driver) — they have negative dynamic resistance.

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Efficiency: modern white LEDs reach 100-200 lm/W (vs incandescent ~15 lm/W).

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Applications: indicator lights, displays, traffic signals, solid-state lighting, fibre-optic communications, OLED displays.

Emitted wavelength

Determines colour. λ = 1240/E_g (nm).

Forward voltage estimate

Approximate; real diodes have additional ohmic drop.

Current-limiting resistor

Designed for the LED's desired forward current (typically 10-20 mA for indicators).

Internal quantum efficiency

High for direct-bandgap; near zero for indirect.

Colour is set by MATERIAL (E_g), not by current or temperature (much).

BLUE LEDs were the hard ones — invented in 1993 (Akasaki, Amano, Nakamura, Nobel 2014). Combined with phosphors made white LEDs feasible.

Always use a series resistor (or driver) with a discrete LED; otherwise it self-destructs at slightly elevated forward voltage.

LEDs degrade gradually (lumen output drops with use) — different from sudden incandescent burnout.

OLEDs use organic semiconductors — flexible, but shorter lifetime.

LED efficiency scales as ~λ/V_F — longer wavelength = higher efficiency. White light via blue + yellow phosphor has typical efficiency 40-50%.

Semiconductor Electronics on sciphylab (also known as SciPhy, SciPhy Lab, SciPhy Labs). Free physics revision for Class 12, JEE Mains, JEE Advanced, NEET UG, AP Physics 1/2/C, SAT Subject Physics, and CUET-UG.